计算化学公社

标题: DLPNO-CCSD(T1)算单电子的化合物有很多警告 [打印本页]

作者
Author:
mfdsrax2    时间: 2022-1-7 09:25
标题: DLPNO-CCSD(T1)算单电子的化合物有很多警告
使用DLPNO-CCSD(T1)计算一个带单电子的化合物,程序给了很多警告,这些需要处理吗?
! DLPNO-CCSD(T1) tightPNO cc-pVTZ cc-pVTZ/C verytightSCF noautostart miniprint nopop
(CPU和内存)

* xyz   0   2
(原子坐标P)
*

WARNING: your system is open-shell and RHF/RKS was chosen
  ===> : WILL SWITCH to UHF/UKS


WARNING: Post HF methods need fully converged wavefunctions
  ===> : Setting SCFConvForced true
         You can overwrite this default with %scf ConvForced false


WARNING: Restarting MDCI calulations with QROs will lead to
         significant changes in the QROs!
  ===> : For restart on a converged wavefunction better use NoIter or MaxIter=0


WARNING: PNO calculations with unrestricted orbitals require UNOs
  ===> : Switching on UNOs

WARNING: Unrestricted DLPNO-CCSD(T0/T) with FullLMP2-Guess requested.
         This is not yet implemented.
         When comparing energies between closed and open shell calculations:
  ===> : Be aware to set UseFullLMP2Guess to false for the corresponding closed shell calculations.
         Note that UseFullLMP2Guess is done by default only for TightPNO closed shell calculations.


WARNING: MDCI localization with Augmented Hessian Foster-Boys
  ===> : Switching off randomization!




作者
Author:
sobereva    时间: 2022-1-7 10:44
不用管
作者
Author:
niobium    时间: 2022-1-7 11:41
这个warning翻译成“提醒”更好。
作者
Author:
sobereva    时间: 2022-1-7 12:01
我觉得ORCA里有些WARNING应该改成NOTE(像GROMACS里WARNING和NOTE就是明确区分的),要不然不懂行的人看到了容易惊慌
作者
Author:
wzkchem5    时间: 2022-1-7 16:36
sobereva 发表于 2022-1-7 05:01
我觉得ORCA里有些WARNING应该改成NOTE(像GROMACS里WARNING和NOTE就是明确区分的),要不然不懂行的人看到 ...

orca里也有个别的note。不过我觉得让用户小心一点比粗心一点好




欢迎光临 计算化学公社 (http://bbs.keinsci.com/) Powered by Discuz! X3.3