各位老师好，初始结构是晶体结构经xTB优化的，我在用ORCA5.0.3计算含Ni金属的配合物的TDDFT时，计算第一个结构成功结束，而在计算第二个、第三个时老是出现相同的错误，我增大了内存，减小核数也不行，之前第一个计算用8000MB内存，30核，正常结束，而计算第二、三结构时，即使改变内存为24000，核数降低为10，也出现错误，请教各位这个问题应该怎么解决，是什么原因导致的，谢谢大家！
输入文件如下：
! B97-3c RIJCOSX tightSCF noautostart miniprint nopop
%maxcore 24000
%pal nprocs 10 end
%tddft
nroots 300
TDA false
end
* xyz 0 1
Ni 4.79354602201531 5.44009503415403 11.23385192720534
Ni 3.09842372261469 4.39861962150431 13.90356790687083
.........
出错界面如下：
[file orca_tools/Tool-Linalg/qcrpasolv.cpp, line 785, Process 0]: Rebuilding of the RPA subspace failed because there are no old eigenvectors, aborting
job aborted:
[ranks] message
[0-9] process exited without calling finalize
---- error analysis -----
[0-9] on DESKTOP-8GUDL4A
D:\ORCA\orca_cis_mpi.exe ended prematurely and may have crashed. exit code 78
---- error analysis -----
ORCA finished by error termination in CIS
Calling Command: mpiexec -np 10 D:\ORCA\orca_cis_mpi.exe NI-c-tddft.cisinp.tmp NI-c-tddft
[file orca_tools/qcmsg.cpp, line 465]:
.... aborting the run