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[综合交流] Which dark state causes photoluminescence quenching

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Hi everyone,
I am studying the photoluminescence (PL) quenching of a complex A1-D-A2. After using electron-hole analysis, for the 1st state, the electron transfers to A1, and for the 2nd state, the electron transfers to A2; both are dark states. Can I ask which one will cause PL quenching? In the experiment, the A2 had better electron withdrawing ability.
Thank you

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